Name | 3-Bromopropene |
Synonyms | BROMALLYLENE ALLYLBROMIDE Allyl bromide ALLYL BROMIDE 3-Bromopropene 3-BROMOPROPENE 3-Bromo Propene 3-bromopropylene 3-BROMOPROPYLENE Propene, 3-bromo- 3-BROMO-1-PROPENE 3-bromoprop-1-ene 3-Bromo-1-propene 2-PROPENYL BROMIDE |
CAS | 106-95-6 |
EINECS | 203-446-6 |
InChI | InChI=1/C3H5Br/c1-2-3-4/h2H,1,3H2 |
InChIKey | BHELZAPQIKSEDF-UHFFFAOYSA-N |
Molecular Formula | C3H5Br |
Molar Mass | 120.98 |
Density | 1.398g/mLat 25°C(lit.) |
Melting Point | -119 °C |
Boling Point | 70-71°C(lit.) |
Flash Point | 28°F |
Water Solubility | insoluble |
Vapor Presure | 18.66kPa at 25℃ |
Vapor Density | 4.2 (vs air) |
Appearance | Liquid |
Specific Gravity | 1.398 |
Color | Clear colorless to slightly colored |
Odor | unpleasant |
Exposure Limit | ACGIH: TWA 0.1 ppm; STEL 0.2 ppm (Skin) |
Merck | 14,288 |
BRN | 605308 |
Storage Condition | 2-8°C |
Stability | Stable. Flammable. Incompatible with strong oxidizing agents. |
Sensitive | Light Sensitive |
Explosive Limit | 4.3-7.3%(V) |
Refractive Index | n20/D 1.469(lit.) |
Physical and Chemical Properties | Boiling Point: 70 - 71 ℃ Melting Point:-119 °c density: 1.39 |
Use | Used as a pharmaceutical Intermediate |
Risk Codes | R11 - Highly Flammable R23/25 - Toxic by inhalation and if swallowed. R34 - Causes burns R50 - Very Toxic to aquatic organisms R25 - Toxic if swallowed R46 - May cause heritable genetic damage R45 - May cause cancer |
Safety Description | S16 - Keep away from sources of ignition. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S60 - This material and its container must be disposed of as hazardous waste. S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. S53 - Avoid exposure - obtain special instructions before use. |
UN IDs | UN 1099 3/PG 1 |
WGK Germany | 2 |
RTECS | UC7090000 |
FLUKA BRAND F CODES | 8-19 |
TSCA | Yes |
HS Code | 29033036 |
Hazard Class | 3 |
Packing Group | I |
Toxicity | LD50 orally in Rabbit: 120 mg/kg |
LogP | 1.79 |
NIST chemical information | information provided by: webbook.nist.gov (external link) |
EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
Use | used in organic synthesis such as synthetic dyes, fragrances; Used in the pharmaceutical industry for the manufacture of cicatriasis; agricultural use as a soil fumigant. organic synthesis, pharmaceutical synthesis intermediates, can be used for the synthesis of the West of barbiturates, dyes, spices; Agriculture for soil fumigation. It is also used as an intermediate for resin modification and fragrance synthesis, household chemicals, emulsion modifiers, silicon products, etc. It has been reported that the polymer that can be polymerized with plasma to form reverse osmosis wax is used in a sealed manned spacecraft; It can also be used as a corrosion inhibitor, catalyst and solvent. bromopropene is used in organic synthesis, and can be used as synthetic dyes and spices; The pharmaceutical industry is used for the preparation of the drug "ceobarbitone"; Agriculture is used as a soil fumigant. This product is used for organic synthesis, can be used for synthetic dyes, spices; Pharmaceutical industry used for the preparation of "Western barbiturates" drugs; Agriculture used as soil fumigant. used as pharmaceutical intermediates |
production method | 1. Obtained by bromination of allyl alcohol: hydrobromic acid was fed into a reaction tank, and sulfuric acid and allyl alcohol were added under stirring. The temperature was heated to reflux for 2H, and the distillate was distilled off when heated to 8 °c, and the 68-73 °c fraction was collected. After washing with water, dehydration with anhydrous sodium sulfate and filtration, allyl bromide was obtained. 2. Bromination of propylene. |
category | flammable liquid |
toxicity grade | high toxicity |
Acute toxicity | oral-rat LD50: 120 mg/kg; Intraperitoneal-mouse LD50: 48 mg/kg |
explosive hazard characteristics | explosive when mixed with air |
flammability hazard characteristics | in case of fire, high temperature, oxidant flammable; hyperthermic decomposition of toxic bromide gas |
storage and transportation characteristics | The warehouse is ventilated and dried at low temperature; It is stored separately from the oxidant |
extinguishing agent | dry powder, dry sand, carbon dioxide, foam, 1211 extinguishing agent |
spontaneous combustion temperature | 554 ° F. |
toxic substance data | information provided by: pubchem.ncbi.nlm.nih.gov (external link) |